There is no easy way to configure a second WAN IP address on a SME server.
Options discussed in the past have included:
1) Extensive customizations to SME to get the existing firewall to allow connections from a secondary WAN address
2) Put an external router that knows how to handle multiple IP addresses in front of the SME server (this is usually discussed in the context of load balancing and redundancy, but could be used in your case if the new router could forward IP_A:443 -> SME:443 (-> server_A:443) and IP_B:443 -> SME:4443 (-> server_B:443)
3)
Proxypass (possibly tricky if the second internal server is running
Outlook Web Access.
4) Set up a second SME server on the new IP address, with DHCP disabled. Use the new SME's LAN address as the default gateway for the second Web server. Optionally, use each SME as an
AFFA backup of the other
5) Use a non-standard port for the second web server:
https://my.smeserver.tld -> server_A:443;
https://my.smeserver.tld:4443 -> server_B:443