But wouldnt the use of port 2525 normally be very little usable ? When most other mail servers in the world sends post on port 25 there will be rather little amounts of mail to be received on port 2525 ?
Correct - SMTP uses port 25 and so changing the port won't result in mail magically being accepted.
However, the original poster asked how to change the SMTP port. I presume they are planning to use an external SMTP redirector host to relay the mail to the non-standard port.
The point still remains that if the ISP won't allow port 25, they probably won't allow you to run a mail server on a non-standard port. If that's the case, you need to change to an ISP who will allow you to run an SMTP server.